Issue 6, 2012

Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

Abstract

We report the first example of catalytic asymmetric direct amination of α-monosubstituted nitroacetates using di-tert-butyl azodicarboxylate. The simple and easily available Hatakeyama's catalyst β-ICD 11 was found to be a highly enantioselective catalyst for this reaction.

Graphical abstract: Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

Supplementary files

Article information

Article type
Communication
Submitted
18 Oct 2011
Accepted
13 Dec 2011
First published
13 Dec 2011

Org. Biomol. Chem., 2012,10, 1158-1161

Direct amination of α-substituted nitroacetates using di-tert-butyl azodicarboxylate catalyzed by Hatakeyama's catalyst β-ICD

C. Ji, Y. Liu, X. Zhao, Y. Guo, H. Wang and J. Zhou, Org. Biomol. Chem., 2012, 10, 1158 DOI: 10.1039/C2OB06746C

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