Issue 23, 2012
From the journal:

RSC Advances

A simple diamine as ligand in iron-catalyzed regioselective allylic alkylation†

Chenguang Yu,a   Aihua Zhoua  and  Jing He*a  

* Corresponding authors

a State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, China
E-mail: jinghe@263.net.cn
Fax: +86-10-64425385
Tel: +86-10-64425280

Abstract

A simple and efficient diamine was found to be an efficient ligand for the iron-catalyzed regioselective allylic alkylation between various allyl carbonates and nucleophiles, affording excellent yields and good regioselectivity (up to 94% and >20 : 1).

Graphical abstract: A simple diamine as ligand in iron-catalyzed regioselective allylic alkylation

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Article information

DOI
https://doi.org/10.1039/C2RA21646A
Article type
Communication
Submitted
01 Aug 2012
Accepted
02 Aug 2012
First published
02 Aug 2012

RSC Adv., 2012,2, 8627-8630

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A simple diamine as ligand in iron-catalyzed regioselective allylic alkylation

C. Yu, A. Zhou and J. He, RSC Adv., 2012, 2, 8627 DOI: 10.1039/C2RA21646A

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