Issue 2, 2013

Relaxations in heterolanthanide dinuclear single-molecule magnets

Abstract

A heterospin dinuclear complex [Dy0.87Yb1.13(H2cht)2Cl4(H2O)(MeCN)]·MeCN shows shifts of the relaxation barriers with respect to the barriers observed in homospin Dy2 and Yb2 isostructural complexes. The origin of slow relaxation in the latter two compounds was elucidated by ab initio calculations.

Graphical abstract: Relaxations in heterolanthanide dinuclear single-molecule magnets

Supplementary files

Article information

Article type
Communication
Submitted
28 Sep 2012
Accepted
08 Nov 2012
First published
08 Nov 2012

Chem. Commun., 2013,49, 158-160

Relaxations in heterolanthanide dinuclear single-molecule magnets

J. Leng, J. Liu, Y. Zheng, L. Ungur, L. F. Chibotaru, F. Guo and M. Tong, Chem. Commun., 2013, 49, 158 DOI: 10.1039/C2CC37036K

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