Issue 13, 2013

Gold-catalysed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation

Abstract

The divergent gold-catalysed reactivity (Csp2–H versus Csp3–H) of aryloxy-tethered allenes has been uncovered.

Graphical abstract: Gold-catalysed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation

Supplementary files

Article information

Article type
Communication
Submitted
30 Oct 2012
Accepted
19 Dec 2012
First published
19 Dec 2012

Chem. Commun., 2013,49, 1282-1284

Gold-catalysed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation

B. Alcaide, P. Almendros, S. Cembellín, T. M. D. Campo and I. Fernández, Chem. Commun., 2013, 49, 1282 DOI: 10.1039/C2CC37872H

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