[Pd(NHC)(PR3)] complexes were shown to be active catalysts in the dehydrogenation of ammonia borane and the subsequent hydrogenation of unsaturated compounds at very low catalyst loadings (0.05 mol% for some substrates).
![Graphical abstract: Tandem ammonia borane dehydrogenation/alkene hydrogenation mediated by [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysts](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C2CC38145A&imageInfo.ImageIdentifier.Year=2013)
C. E. Hartmann, V. Jurčík, O. Songis and C. S. J. Cazin, Chem. Commun., 2013, 49, 1005 DOI: 10.1039/C2CC38145A
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