Issue 24, 2013
From the journal:

Chemical Communications

Nickel-catalysed novel β,γ-unsaturated nitrile synthesis†

Shan Tang,‡a   Chao Liu‡a  and  Aiwen Lei*ab  

* Corresponding authors

a College of Chemistry and Molecular Sciences, Wuhan University, P. R. China
E-mail: aiwenlei@whu.edu.cn
Fax: +86-27-68754067
Tel: +86-27-68754672

b Laboratory of Chemical Genomics, School of Chemical Biology and Biotechnology, Peking University Shenzhen Graduate School, Shenzhen 518055, China

Abstract

Through a nickel-catalysed Heck-type reaction, a direct coupling of alkenes with α-cyano alkyl bromides was achieved. This procedure provides a novel way for the synthesis of β,γ-unsaturated nitriles.

Graphical abstract: Nickel-catalysed novel β,γ-unsaturated nitrile synthesis

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Article information

DOI
https://doi.org/10.1039/C3CC00029J
Article type
Communication
Submitted
02 Jan 2013
Accepted
01 Feb 2013
First published
04 Feb 2013

Chem. Commun., 2013,49, 2442-2444

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Nickel-catalysed novel β,γ-unsaturated nitrile synthesis

S. Tang, C. Liu and A. Lei, Chem. Commun., 2013, 49, 2442 DOI: 10.1039/C3CC00029J

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