A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a μ2-bridging coordination mode

Holger Braunschweig; Rüdiger Bertermann; Alexander Damme; Thomas Kupfer

doi:10.1039/C3CC38686D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a μ₂-bridging coordination mode†

Holger Braunschweig,*^a Rüdiger Bertermann,^a Alexander Damme^a and Thomas Kupfer^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg, Germany
E-mail: h.braunschweig@uni-wuerzburg.de
Fax: +49 931 31 84623

Abstract

A novel μ₂-bridging coordination mode of the diboran(4)-1,2-diyl ligand was unveiled for dinuclear 1, in which two Pt(II) centers are connected by the diboran(4)yl moiety. Prolonged heating resulted in the unprecedented reductive elimination of the haloborane from one Pt(II) center to afford mononuclear 2.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C3CC38686D
Article type: Communication
Submitted: 04 Dec 2012
Accepted: 04 Feb 2013
First published: 06 Feb 2013

Download Citation

Chem. Commun., 2013,49, 2439-2441

Permissions

Request permissions

A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a μ₂-bridging coordination mode

H. Braunschweig, R. Bertermann, A. Damme and T. Kupfer, Chem. Commun., 2013, 49, 2439 DOI: 10.1039/C3CC38686D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications