Issue 42, 2013

Synthesis of optically pure [60]fullerene e,e,e-tris adducts

Abstract

The reaction of readily available optically active Si-tethered tris(malonates) with C60 gave easily separable diastereoisomers differing by the absolute configuration of the inherently chiral addition pattern on the fullerene core. The absolute configuration of the e,e,e addition pattern has been unambiguously determined using X-ray crystal structure analysis.

Graphical abstract: Synthesis of optically pure [60]fullerene e,e,e-tris adducts

Supplementary files

Article information

Article type
Communication
Submitted
23 Feb 2013
Accepted
08 Apr 2013
First published
19 Apr 2013

Chem. Commun., 2013,49, 4752-4754

Synthesis of optically pure [60]fullerene e,e,e-tris adducts

S. Guerra, F. Schillinger, D. Sigwalt, M. Holler and J. Nierengarten, Chem. Commun., 2013, 49, 4752 DOI: 10.1039/C3CC41409D

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