The first total synthesis of (8R,6′R)-peridinin-5,8-furanoxide, a C37 xanthophyll norcarotenoid, has been achieved. The key steps of the synthetic sequence are a Julia–Kocienski condensation and a late stage stereoretentive Stille cross-coupling of an iodoallene.
L. Otero, B. Vaz, R. Álvarez and Á. R. de Lera, Chem. Commun., 2013, 49, 5043 DOI: 10.1039/C3CC41552J
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