Issue 53, 2013
From the journal:

Chemical Communications

Reshaping molecules through cocrystallization. Comparison of the structures of Hg{Co(CO)4}2 and Hg{Co(CO)4}2·C60·toluene†

Faye L. Bowles,a   Marilyn M. Olmstead,a   Christine M. Beaversb  and  Alan L. Balch*a  

* Corresponding authors

a Department of Chemistry, University of California, One Shields Avenue, Davis, CA, 95616, USA
E-mail: albalch@ucdavis.edu
Fax: +1 (530)752 2820
Tel: +1 (530)752 0941

b Advanced Light Source, Lawrence Berkeley National Lab, One Cyclotron Road, Berkeley, CA, 94720, USA

Abstract

Cocrystallization of Hg{Co(CO)4}2 with C60 produces Hg{Co(CO)4}2·C60·toluene in which the geometry of the Hg{Co(CO)4}2 molecule is rearranged to fit between the remarkably well ordered fullerenes.

Graphical abstract: Reshaping molecules through cocrystallization. Comparison of the structures of Hg{Co(CO)4}2 and Hg{Co(CO)4}2·C60·toluene

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Article information

DOI
https://doi.org/10.1039/C3CC41773E
Article type
Communication
Submitted
08 Mar 2013
Accepted
25 Apr 2013
First published
26 Apr 2013

Chem. Commun., 2013,49, 5921-5923

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Reshaping molecules through cocrystallization. Comparison of the structures of Hg{Co(CO)4}2 and Hg{Co(CO)4}2·C60·toluene

F. L. Bowles, M. M. Olmstead, C. M. Beavers and A. L. Balch, Chem. Commun., 2013, 49, 5921 DOI: 10.1039/C3CC41773E

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