Issue 73, 2013
From the journal:

Chemical Communications

One pot synthesis of poly(3-hexylthiophene)-block-poly(hexadecyloxylallene) by sequential monomer addition†

Zong-Quan Wu,*a   Yu Chen,a   Ying Wang,a   Xiao-Yue He,a   Yun-Sheng Dinga  and  Na Liua  

* Corresponding authors

a Department of Polymer Science and Engineering, School of Chemical Engineering, Hefei University of Technology and Key Laboratory of Advanced Functional Materials and Devices, Anhui, Anhui Province, China 230009
E-mail: zqwu@hfut.edu.cn

Abstract

A series of poly(3-hexylthiophene)-b-poly(hexadecyloxylallene) copolymers has been synthesized in one pot via sequential monomer addition by using Ni(dppp)Cl2 as a single catalyst. The copolymerization has been revealed to proceed by a controlled chain extension mechanism and the block copolymer can self-assemble into a well-defined supramolecular structure in solution and exhibit microphase separation in the solid state.

Graphical abstract: One pot synthesis of poly(3-hexylthiophene)-block-poly(hexadecyloxylallene) by sequential monomer addition

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Article information

DOI
https://doi.org/10.1039/C3CC43026J
Article type
Communication
Submitted
24 Apr 2013
Accepted
12 Jul 2013
First published
12 Jul 2013

Chem. Commun., 2013,49, 8069-8071

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One pot synthesis of poly(3-hexylthiophene)-block-poly(hexadecyloxylallene) by sequential monomer addition

Z. Wu, Y. Chen, Y. Wang, X. He, Y. Ding and N. Liu, Chem. Commun., 2013, 49, 8069 DOI: 10.1039/C3CC43026J

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