Issue 73, 2013
From the journal:

Chemical Communications

Rh-catalyzed sulfonic acid group directed ortho C–H olefination of arenes†

Yi Donga  and  Gang Liu*abc  

* Corresponding authors

a Institute of Materia Medica, Chinese Academy of Medical Sciences & Peking Union Medical College, 2 Nanwei Rd, Xicheng Dist, Beijing 100050, P. R. China

b Tsinghua-Peking Center for Life Sciences, Tsinghua University, Haidian Dist, Beijing 100084, P. R. China

c Department of Pharmacology and Pharmaceutical Sciences, School of Medicine, Tsinghua University, Haidian Dist, Beijing 100084, P. R. China
E-mail: gangliu27@biomed.tsinghua.edu.cn
Fax: +86 010 63165246
Tel: +86 010 63165246

Abstract

A Rh-catalyzed ortho C–H olefination of arenes directed by a sulfonic acid group was developed with good yields and a broad reaction scope. Efficient performance of the catalyst caused this electron-poor aromatic C–H to be activated effectively and unactivated alkenes are also suitable for this reaction.

Graphical abstract: Rh-catalyzed sulfonic acid group directed ortho C–H olefination of arenes

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Article information

DOI
https://doi.org/10.1039/C3CC44690E
Article type
Communication
Submitted
24 Jun 2013
Accepted
10 Jul 2013
First published
12 Jul 2013

Chem. Commun., 2013,49, 8066-8068

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Rh-catalyzed sulfonic acid group directed ortho C–H olefination of arenes

Y. Dong and G. Liu, Chem. Commun., 2013, 49, 8066 DOI: 10.1039/C3CC44690E

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