Issue 70, 2013
From the journal:

Chemical Communications

Two homochiral organocatalytic metal organic materials with nanoscopic channels†

Zhuxiu Zhang,‡a   Young Ran Ji,‡a   Lukasz Wojtas,a   Wen-Yang Gao,a   Shengqian Ma,a   Michael J. Zaworotko*a  and  Jon C. Antilla*a  

* Corresponding authors

a Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE 205, Tampa, Florida 33620, USA
E-mail: xtal@usf.edu, jantilla@usf.edu

Abstract

Two homochiral organocatalytic MOMs were prepared using tetra- and octa-carboxylate ligands, respectively. The nanoscopic channels in these MOMs are lined by organonocatalytic chiral phosphoric acid derivatives of binol and ocMOM-1 exhibited improved enantioselectivity over the parent ligand in the context of transfer hydrogenation of a series of benzoxazines.

Graphical abstract: Two homochiral organocatalytic metal organic materials with nanoscopic channels

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Article information

DOI
https://doi.org/10.1039/C3CC43801E
Article type
Communication
Submitted
20 May 2013
Accepted
12 Jul 2013
First published
12 Jul 2013

Chem. Commun., 2013,49, 7693-7695

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Two homochiral organocatalytic metal organic materials with nanoscopic channels

Z. Zhang, Y. R. Ji, L. Wojtas, W. Gao, S. Ma, M. J. Zaworotko and J. C. Antilla, Chem. Commun., 2013, 49, 7693 DOI: 10.1039/C3CC43801E

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