Issue 81, 2013
From the journal:

Chemical Communications

Unprecedented ferromagnetic dipolar interaction in a dinuclear holmium(iii) complex: a combined experimental and theoretical study†

Ji-Dong Leng,a   Jun-Liang Liu,a   Wei-Quan Lin,a   Silvia Gómez-Coca,b   Daniel Aravena,b   Eliseo Ruiz*b  and  Ming-Liang Tong*a  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: tongml@mail.sysu.edu.cn

b Departament de Química Inorgànica and Institut de Recerca de Química Teòrica i Computacional, Universitat de Barcelona, Diagonal 645, E-08028 Barcelona, Spain
E-mail: eliseo.ruiz@qi.ub.es

Abstract

A ferromagnetic intramolecular dipolar interaction is observed and verified by both experimental studies and ab initio calculations on a dinuclear holmium(III) complex [Ho2(H2cht)2Cl4(H2O)(MeCN)]·MeCN.

Graphical abstract: Unprecedented ferromagnetic dipolar interaction in a dinuclear holmium(iii) complex: a combined experimental and theoretical study

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Article information

DOI
https://doi.org/10.1039/C3CC45113E
Article type
Communication
Submitted
08 Jul 2013
Accepted
12 Aug 2013
First published
13 Aug 2013

Chem. Commun., 2013,49, 9341-9343

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Unprecedented ferromagnetic dipolar interaction in a dinuclear holmium(III) complex: a combined experimental and theoretical study

J. Leng, J. Liu, W. Lin, S. Gómez-Coca, D. Aravena, E. Ruiz and M. Tong, Chem. Commun., 2013, 49, 9341 DOI: 10.1039/C3CC45113E

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