Issue 82, 2013
From the journal:

Chemical Communications

Ruthenium-catalyzed olefin metathesis accelerated by the steric effect of the backbone substituent in cyclic (alkyl)(amino) carbenes†

Jun Zhang,*a   Shangfei Song,a   Xiao Wang,a   Jiajun Jiaoa  and  Min Shi*ab  

* Corresponding authors

a Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Mei Long Road, Shanghai 200237, China
E-mail: zhangj@ecust.edu.cn
Tel: +86 021 64252995

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China
E-mail: mshi@mail.sioc.ac.cn
Tel: +86 021 64252995

Abstract

Three ruthenium complexes bearing backbone-monosubstituted CAACs were prepared and displayed dramatic improvement in catalytic efficiency not only in RCM reaction but also in the ethenolysis of methyl oleate, compared to those bearing backbone-disubstituted CAACs.

Graphical abstract: Ruthenium-catalyzed olefin metathesis accelerated by the steric effect of the backbone substituent in cyclic (alkyl)(amino) carbenes

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Article information

DOI
https://doi.org/10.1039/C3CC45823G
Article type
Communication
Submitted
30 Jul 2013
Accepted
12 Aug 2013
First published
14 Aug 2013

Chem. Commun., 2013,49, 9491-9493

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Ruthenium-catalyzed olefin metathesis accelerated by the steric effect of the backbone substituent in cyclic (alkyl)(amino) carbenes

J. Zhang, S. Song, X. Wang, J. Jiao and M. Shi, Chem. Commun., 2013, 49, 9491 DOI: 10.1039/C3CC45823G

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