Issue 99, 2013
From the journal:

Chemical Communications

Synthesis of α,β-unsaturated carbonyl compounds via a visible-light-promoted organocatalytic aerobic oxidation†

Junlin Zhang,a   Leming Wang,a   Qi Liu,a   Zhen Yang*ab  and  Yong Huang*a  

* Corresponding authors

a Key Laboratory of Chemical Genomics, School of Chemical Biology and Biotechnology, Peking University, Shenzhen Graduate School, Shenzhen, China

b Key Laboratory of Bioorganic Chemistry and Molecular Engineering, Minster of Education and Beijing National Laboratories for Molecular Science, College of Chemistry, Peking University, Beijing 100871, China
E-mail: zyang@pku.edu.cn, huangyong@pkusz.edu.cn

Abstract

α,β-Unsaturated ketones and aldehydes have been synthesized from their corresponding silyl enol ethers in a straightforward protocol involving a visible-light promoted organocatalytic, aerobic oxidation reaction. A cheap organic dye was used catalytically in these reactions as the photosensitizer.

Graphical abstract: Synthesis of α,β-unsaturated carbonyl compounds via a visible-light-promoted organocatalytic aerobic oxidation

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Article information

DOI
https://doi.org/10.1039/C3CC46778C
Article type
Communication
Submitted
05 Sep 2013
Accepted
18 Oct 2013
First published
21 Oct 2013

Chem. Commun., 2013,49, 11662-11664

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Synthesis of α,β-unsaturated carbonyl compounds via a visible-light-promoted organocatalytic aerobic oxidation

J. Zhang, L. Wang, Q. Liu, Z. Yang and Y. Huang, Chem. Commun., 2013, 49, 11662 DOI: 10.1039/C3CC46778C

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