Issue 33, 2013
From the journal:

Physical Chemistry Chemical Physics

Non-humidified proton conduction between a Lewis acid–base pair†

Takaya Ogawa,a   Hidenori Ohashi,a   Takanori Tamakia  and  Takeo Yamaguchi*a  

* Corresponding authors

a Chemical Resources Laboratory, Tokyo Institute of Technology, R1-17, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
E-mail: yamag@res.titech.ac.jp

Abstract

Proton conduction in zirconium sulphate (ZrSO4) composed of a Lewis acid–base pair was studied. ZrSO4 exhibits non-humidified proton conductivity, comparable to other proton conductors under similar conditions. Ab initio calculation shows that a proton transfers in ZrSO4 from a Lewis acid to a Lewis base without a proton carrier.

Graphical abstract: Non-humidified proton conduction between a Lewis acid–base pair

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Article information

DOI
https://doi.org/10.1039/C3CP51697K
Article type
Communication
Submitted
20 Apr 2013
Accepted
18 Jun 2013
First published
11 Jul 2013

Phys. Chem. Chem. Phys., 2013,15, 13814-13817

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Non-humidified proton conduction between a Lewis acid–base pair

T. Ogawa, H. Ohashi, T. Tamaki and T. Yamaguchi, Phys. Chem. Chem. Phys., 2013, 15, 13814 DOI: 10.1039/C3CP51697K

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