Issue 10, 2013
From the journal:

Dalton Transactions

A cyclopalladated complex of corannulene with a pyridine pendant and its columnar self-assembly†

Mihoko Yamada,a   Shohei Tashiro,a   Ryosuke Miyakeb  and  Mitsuhiko Shionoya*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: shionoya@chem.s.u-tokyo.ac.jp
Fax: +81 03 5841 8061
Tel: +81 03 5841 8061

b Department of Chemistry and Biochemistry, Graduate School of Humanities and Science, Ochanomizu University, 2-1-1 Otsuka, Bunkyo-ku, Tokyo 112-8610, Japan

Abstract

Bowl-shaped corannulene provides various metal binding modes with its curved π-surfaces and rim. Herein, we report the syntheses of 2-pyridylcorannulene and its cyclopalladated complex. Its expanded π-system and columnar self-assembly in the crystal state were revealed by NMR and UV-vis spectroscopies, ESI-TOF mass spectrometry and single-crystal X-ray analysis.

Graphical abstract: A cyclopalladated complex of corannulene with a pyridine pendant and its columnar self-assembly

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Article information

DOI
https://doi.org/10.1039/C2DT32883F
Article type
Communication
Submitted
01 Dec 2012
Accepted
04 Jan 2013
First published
07 Jan 2013

Dalton Trans., 2013,42, 3300-3303

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A cyclopalladated complex of corannulene with a pyridine pendant and its columnar self-assembly

M. Yamada, S. Tashiro, R. Miyake and M. Shionoya, Dalton Trans., 2013, 42, 3300 DOI: 10.1039/C2DT32883F

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