An unprecedented octahedral {Cd30} nanocage supported by twelve pendant-armed tetraacetate macrocyclic ligands

Wei-Jie Gong; Ying-Ying Liu; Jin Yang; Hua Wu; Jian-Fang Ma; Teng-Feng Xie

doi:10.1039/C3DT32801E

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An unprecedented octahedral {Cd₃₀} nanocage supported by twelve pendant-armed tetraacetate macrocyclic ligands†

Wei-Jie Gong,^a Ying-Ying Liu,*^a Jin Yang,^a Hua Wu,^a Jian-Fang Ma*^a and Teng-Feng Xie^b

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* Corresponding authors

^a Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China
E-mail: liuyy21@yahoo.com.cn, jianfangma@yahoo.com.cn
Fax: +86-431-85098620
Tel: +86-431-85098620

^b College of Chemistry, Jilin University, Changchun, People's Republic of China

Abstract

An unprecedented octahedral {Cd₃₀} nanocage supported by twelve pendant-armed tetraacetate macrocyclic ligands was synthesized through the reaction of macrocyclic tetraethyl ester and Cd(OAc)₂·2H₂O in a 1 : 2 stoichiometry, where the surface photovoltage and photoluminescent properties have been studied for the nanocage.

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Article information

DOI: https://doi.org/10.1039/C3DT32801E
Article type: Communication
Submitted: 23 Nov 2012
Accepted: 07 Jan 2013
First published: 22 Jan 2013

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Dalton Trans., 2013,42, 3304-3307

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An unprecedented octahedral {Cd₃₀} nanocage supported by twelve pendant-armed tetraacetate macrocyclic ligands

W. Gong, Y. Liu, J. Yang, H. Wu, J. Ma and T. Xie, Dalton Trans., 2013, 42, 3304 DOI: 10.1039/C3DT32801E

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Dalton Transactions