Issue 22, 2013
From the journal:

Dalton Transactions

A water soluble Mn(ii) polymer with aqua metal bridges†

Mònica Fontanet,a   Montserrat Rodríguez,a   Isabel Romero,*a   Xavier Fontrodona,a   Francesc Teixidor,*b   Clara Viñas,b   Núria Aliaga-Alcaldecd  and  Pavel Matějíčeke  

* Corresponding authors

a Departament de Química and Serveis Tècnics de Recerca, Universitat de Girona, Campus de Montilivi, E-17071 Girona, Spain
E-mail: marisa.romero@udg.edu
Fax: +34 972 418150
Tel: +34 972 418262

b Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus UAB, E-08193 Bellaterra, Spain
E-mail: teixidor@icmab.es

c Universitat de Barcelona, Diagonal 645, E-08028 Barcelona, Spain

d ICREA-Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus de la UAB, 08193 Bellaterra, Spain

e Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University in Prague, Hlavova 2030, 128 40 Prague 2, Czech Republic

Abstract

The first water soluble and crystallographically determined polynuclear Mn(II) complex, with water molecules bridging every two Mn centers, is reported. This is an unusual feature in 1D oligomer Mn(II) compounds with a nuclearity higher than 2. The polymer structure is largely preserved in water.

Graphical abstract: A water soluble Mn(ii) polymer with aqua metal bridges

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Article information

DOI
https://doi.org/10.1039/C3DT00097D
Article type
Communication
Submitted
11 Jan 2013
Accepted
12 Feb 2013
First published
13 Feb 2013

Dalton Trans., 2013,42, 7838-7841

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A water soluble Mn(II) polymer with aqua metal bridges

M. Fontanet, M. Rodríguez, I. Romero, X. Fontrodona, F. Teixidor, C. Viñas, N. Aliaga-Alcalde and P. Matějíček, Dalton Trans., 2013, 42, 7838 DOI: 10.1039/C3DT00097D

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