Issue 22, 2013
From the journal:

Dalton Transactions

Reactivity comparison of high-valent iron(iv)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size†

Seungwoo Hong,‡a   Hee So,‡a   Heejung Yoon,ab   Kyung-Bin Cho,a   Yong-Min Lee,a   Shunichi Fukuzumi*ab  and  Wonwoo Nam*a  

* Corresponding authors

a Department of Bioinspired Science, Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea
E-mail: wwnam@ewha.ac.kr

b Department of Material and Life Science, Osaka University and ALCA (JST), 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan
E-mail: fukuzumi@chem.eng.osaka-u.ac.jp

Abstract

The ring size effect of macrocyclic TMC ligands in nonheme iron(IV)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(IV)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high FeIV/III redox potential.

Graphical abstract: Reactivity comparison of high-valent iron(iv)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

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Article information

DOI
https://doi.org/10.1039/C3DT50750E
Article type
Communication
Submitted
20 Mar 2013
Accepted
28 Mar 2013
First published
03 Apr 2013

Dalton Trans., 2013,42, 7842-7845

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Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

S. Hong, H. So, H. Yoon, K. Cho, Y. Lee, S. Fukuzumi and W. Nam, Dalton Trans., 2013, 42, 7842 DOI: 10.1039/C3DT50750E

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