Issue 45, 2013
From the journal:

Dalton Transactions

Programmed crystallizationvia epitaxial growth and ligand replacement towards hybridizing porous coordination polymer crystals†

Kenji Hirai,a   Kebi Chen,a   Tomohiro Fukushima,a   Satoshi Horike,a   Mio Kondo,bc   Nicolas Louvain,bc   Chiwon Kim,a   Yoko Sakata,bc   Mikhail Meilikhov,b   Osami Sakata,d   Susumu Kitagawa*abc  and  Shuhei Furukawa*bc  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, Japan
E-mail: kitagawa@sbchem.kyoto-u.ac.jp
Fax: +81-75-383-2732
Tel: +81-75-383-2733

b Institute for Integrated Cell-Material Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto, Japan
E-mail: shuhei.furukawa@icems.kyoto-u.ac.jp
Fax: +81-75-753-9820
Tel: +81-75-753-9868

c ERATO Kitagawa Integrated Pores Project, Japan Science and Technology Agency (JST), Kyoto Research Park bldg #3, Shimogyo-ku, Kyoto, Japan

d Synchrotron X-ray Station at Spring-8, National Institute for Materials Science (NIMS), Sayo, Hyogo 679-5148, Japan

Abstract

Hybridized porous coordination polymers (PCPs) are synthesized through epitaxial growth or ligand replacement. Whereas epitaxial growth on the core crystal leads to a sandwich type PCP, ligand replacement near the surface of core crystal results in a core–shell type PCP.

Graphical abstract: Programmed crystallization via epitaxial growth and ligand replacement towards hybridizing porous coordination polymer crystals

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Article information

DOI
https://doi.org/10.1039/C3DT50679G
Article type
Communication
Submitted
12 Mar 2013
Accepted
05 Apr 2013
First published
08 Apr 2013

Dalton Trans., 2013,42, 15868-15872

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Programmed crystallization via epitaxial growth and ligand replacement towards hybridizing porous coordination polymer crystals

K. Hirai, K. Chen, T. Fukushima, S. Horike, M. Kondo, N. Louvain, C. Kim, Y. Sakata, M. Meilikhov, O. Sakata, S. Kitagawa and S. Furukawa, Dalton Trans., 2013, 42, 15868 DOI: 10.1039/C3DT50679G

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