Issue 45, 2013
From the journal:

Dalton Transactions

Synthesis of a hetero-dinuclear metal complex in a porphyrin/phthalocyanine four-fold rotaxane†

Yasuyuki Yamada,ab   Nozomi Miharab  and  Kentaro Tanaka*bc  

* Corresponding authors

a Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan

b Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan
E-mail: kentaro@chem.nagoya-u.ac.jp
Fax: +81-52-789-2940
Tel: +81-52-789-2940

c CREST, Japan Science and Technology Agency, Honcho 4-1-8, Kawaguchi-shi, Saitama 332-0012, Japan

Abstract

We report synthesis of a hetero-dinuclear metal complex in a four-fold rotaxane, in which a Cu2+–porphyrin and a Zn2+–phthalocyanine are cofacially stacked. Interaction between the two metal complexes in the rotaxane was investigated by a UV-Vis absorption spectral study.

Graphical abstract: Synthesis of a hetero-dinuclear metal complex in a porphyrin/phthalocyanine four-fold rotaxane

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Article information

DOI
https://doi.org/10.1039/C3DT51043C
Article type
Communication
Submitted
20 Apr 2013
Accepted
14 May 2013
First published
04 Jun 2013

Dalton Trans., 2013,42, 15873-15876

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Synthesis of a hetero-dinuclear metal complex in a porphyrin/phthalocyanine four-fold rotaxane

Y. Yamada, N. Mihara and K. Tanaka, Dalton Trans., 2013, 42, 15873 DOI: 10.1039/C3DT51043C

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