Issue 15, 2014
From the journal:

Chemical Communications

Reversible crystal-to-amorphous-to-crystal phase transition and a large magnetocaloric effect in a spongelike metal organic framework material†

Chong-Bin Tian,ab   Rui-Ping Chen,a   Chao He,a   Wei-Jin Li,ab   Qi Wei,ab   Xu-Dong Zhanga  and  Shao-Wu Du*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou 350002, P. R. China
E-mail: swdu@fjirsm.ac.cn
Fax: +86 591 83709470

b University of Chinese Academy of Sciences, Beijing 100039, P. R. China

Abstract

Reversible crystal-to-amorphous-to-crystal phase transition accompanied by changes in magnetic and NLO properties was first observed in a rigid non-porous spongelike MOF material. The crystal phase exhibits a high magnetocaloric effect, while the amorphous phase has potential application as a magnetic DMF sensor.

Graphical abstract: Reversible crystal-to-amorphous-to-crystal phase transition and a large magnetocaloric effect in a spongelike metal organic framework material

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Article information

DOI
https://doi.org/10.1039/C3CC48325H
Article type
Communication
Submitted
30 Oct 2013
Accepted
17 Dec 2013
First published
18 Dec 2013

Chem. Commun., 2014,50, 1915-1917

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Reversible crystal-to-amorphous-to-crystal phase transition and a large magnetocaloric effect in a spongelike metal organic framework material

C. Tian, R. Chen, C. He, W. Li, Q. Wei, X. Zhang and S. Du, Chem. Commun., 2014, 50, 1915 DOI: 10.1039/C3CC48325H

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