Nickel(II) complexes of (M : L) stoichiometries 1 : 1 (1) and 1 : 2 (2) were prepared from a polydentate ligand involving diiminosemiquinonate radicals. Both were characterized by X-ray diffraction, Vis-NIR and EPR spectroscopy as well as electrochemistry. Ligand-centered oxidation of 1 promotes ligand ejection to give 2.
N. Leconte, J. Ciccione, G. Gellon, C. Philouze and F. Thomas, Chem. Commun., 2014, 50, 1918 DOI: 10.1039/C3CC48549H
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