Issue 8, 2014
From the journal:

Chemical Communications

Enhancement of spin-crossover cooperativity mediated by lone pair–π interactions and halogen bonding†

Nassim Nassirinia,ab   Saeid Amani,b   Simon J. Teat,c   Olivier Roubeau*d  and  Patrick Gamez*ae  

* Corresponding authors

a Departament de Química Inorgànica, QBI, Universitat de Barcelona, Martí i Franquès 1-11, 08028 Barcelona, Spain
E-mail: patrick.gamez@qi.ub.es
Web: www.bio-inorganic-chemistry-icrea-ub.com
Fax: +34 934907725

b Arak University, Faculty of Sciences, Department of Chemistry, Arak 38156-8-8349, Iran

c Advanced Light Source (ALS), Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA

d Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC and Universidad de Zaragoza, Plaza San Francisco s/n, 50009 Zaragoza, Spain
E-mail: roubeau@unizar.es

e Institució Catalana de Recerca i Estudis Avançats (ICREA), Passeig Lluís Companys 23, 08010 Barcelona, Spain

Abstract

Rational ligand design has allowed the generation of a highly cooperative spin-transition iron(II) complex, an unprecedented result in the family of (2,2′-dipyridylamino/s-triazine)-based SCO materials.

Graphical abstract: Enhancement of spin-crossover cooperativity mediated by lone pair–π interactions and halogen bonding

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Article information

DOI
https://doi.org/10.1039/C3CC48334G
Article type
Communication
Submitted
30 Oct 2013
Accepted
29 Nov 2013
First published
02 Dec 2013

Chem. Commun., 2014,50, 1003-1005

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Enhancement of spin-crossover cooperativity mediated by lone pair–π interactions and halogen bonding

N. Nassirinia, S. Amani, S. J. Teat, O. Roubeau and P. Gamez, Chem. Commun., 2014, 50, 1003 DOI: 10.1039/C3CC48334G

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