Issue 49, 2014
From the journal:

Chemical Communications

An unexpected role of the monodentate ligand in photocatalytic hydrogen production of the pentadentate ligand-based cobalt complexes†

Jingfan Xie,ab   Qianxiong Zhou,a   Chao Li,a   Weibo Wang,a   Yuanjun Hou,*a   Baowen Zhanga  and  Xuesong Wang*a  

* Corresponding authors

a Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: xswang@mail.ipc.ac.cn, yuanjunhou@yahoo.com
Fax: +86-10-62564049
Tel: +86-10-82543592

b Graduate School of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

The dissociation of one pyridine of a pentadentate ligand (N4Py) from the Co centre was found to be responsible for the formation of a Co(III) hydride species, an indispensable intermediate for photocatalytic proton reduction.

Graphical abstract: An unexpected role of the monodentate ligand in photocatalytic hydrogen production of the pentadentate ligand-based cobalt complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4CC01471E
Article type
Communication
Submitted
26 Feb 2014
Accepted
29 Mar 2014
First published
31 Mar 2014

Chem. Commun., 2014,50, 6520-6522

Permissions

Request permissions

An unexpected role of the monodentate ligand in photocatalytic hydrogen production of the pentadentate ligand-based cobalt complexes

J. Xie, Q. Zhou, C. Li, W. Wang, Y. Hou, B. Zhang and X. Wang, Chem. Commun., 2014, 50, 6520 DOI: 10.1039/C4CC01471E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements