Intramolecular N–H⋯Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex

Jesse V. Gavette; Christina M. Klug; Lev N. Zakharov; Matthew P. Shores; Michael M. Haley; Darren W. Johnson

doi:10.1039/C4CC02297A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Intramolecular N–H⋯Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl₂ complex†

Jesse V. Gavette,^a Christina M. Klug,^b Lev N. Zakharov,^c Matthew P. Shores,*^b Michael M. Haley*^a and Darren W. Johnson*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry & Biochemistry and Materials Science Institute, University of Oregon, Eugene, OR 97403-1253, USA
E-mail: dwj@uoregon.edu, haley@uoregon.edu
Tel: +1-541-346-1253

^b Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA
E-mail: matthew.shores@colostate.edu
Tel: +1-970-491-7235

^c CAMCOR—Center for Advanced Materials Characterization in Oregon, University of Oregon, Eugene, OR 97403-1253, USA

Abstract

A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl₂ complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C4CC02297A
Article type: Communication
Submitted: 28 Mar 2014
Accepted: 14 May 2014
First published: 15 May 2014
This article is Open Access

Download Citation

Chem. Commun., 2014,50, 7173-7175

Author version available

Download author version (PDF)

Permissions

Request permissions

Intramolecular N–H⋯Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl₂ complex

J. V. Gavette, C. M. Klug, L. N. Zakharov, M. P. Shores, M. M. Haley and D. W. Johnson, Chem. Commun., 2014, 50, 7173 DOI: 10.1039/C4CC02297A

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications