pH-responsive perylene-ended amphiphilic homopolymers can self-assemble into flower-like structures by pH-adjustment. Both the π–π stacking of perylene end groups and the electrostatic repulsion effect of the polymer chains contribute to the pH-responsive self-assembly in aqueous solution.
J. Zhang, S. You, S. Yan, K. Müllen, W. Yang and M. Yin, Chem. Commun., 2014, 50, 7511 DOI: 10.1039/C4CC02448F
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