Issue 61, 2014

A combination of the “pillaring” strategy and chiral induction: an approach to prepare homochiral three-dimensional coordination polymers from achiral precursors

Abstract

Utilizing enantiopure camphorsulfonic acid as a chiral induction agent, 3D homochiral complexes were obtained from achiral 2D layers and MoO42− pillars. This methodology combines the “pillaring” strategy with chiral induction, providing a new way to synthesize homochiral 3D coordination polymers intentionally from achiral precursors.

Graphical abstract: A combination of the “pillaring” strategy and chiral induction: an approach to prepare homochiral three-dimensional coordination polymers from achiral precursors

Supplementary files

Article information

Article type
Communication
Submitted
08 May 2014
Accepted
05 Jun 2014
First published
09 Jun 2014

Chem. Commun., 2014,50, 8320-8323

A combination of the “pillaring” strategy and chiral induction: an approach to prepare homochiral three-dimensional coordination polymers from achiral precursors

Y. Wen, T. Sheng, Z. Sun, Z. Xue, Y. Wang, Y. Wang, S. Hu, X. Ma and X. Wu, Chem. Commun., 2014, 50, 8320 DOI: 10.1039/C4CC03478C

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