The Pd/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination with a wide range of O- and N-nucleophiles have been developed (up to 97% yield, 98.5% ee). The products can also be conveniently transformed into biologically active chiral heterocycles.
B. Feng, H. Cheng, J. Chen, Q. Deng, L. Lu and W. Xiao, Chem. Commun., 2014, 50, 9550 DOI: 10.1039/C4CC03920C
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