The phosphorylation of the ortho C–H bonds in benzamides containing an 8-aminoquinoline moiety as a bidentate directing group with H-phosphonates using copper as a catalyst under mild temperature conditions is described. This method shows high functional group compatibility and selectively gives mono-substituted products.
S. Wang, R. Guo, G. Wang, S. Chen and X. Yu, Chem. Commun., 2014, 50, 12718 DOI: 10.1039/C4CC06246A
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