Issue 19, 2014
From the journal:

Dalton Transactions

Dehydration-triggered magnetic phase conversion in the porous Cu(ii)Mn(iii) metal–organic framework†

Dae Won Ryu,a   Jin Ho Shin,a   Kwang Soo Lim,a   Woo Ram Lee,a   Won Ju Phang,a   Sung Won Yoon,b   Byoung Jin Suh,b   Eui Kwan Kohc  and  Chang Seop Hong*a  

* Corresponding authors

a Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-713, Korea
E-mail: cshong@korea.ac.kr

b Department of Physics, The Catholic University of Korea, Buchon 420-743, Korea

c Nano-Bio System Research Team, Korea Basic Science Institute, Seoul 136-713, Korea

Abstract

Dehydration of the three-dimensional Cu(II)–Mn(III) coordination network undergoes a dramatic magnetic phase transformation from a paramagnetic state to a long-range magnetic ordered phase with glassy behavior. The gas adsorption behavior and re-entrant spin glass character are uniquely apparent in the dehydrated sample.

Graphical abstract: Dehydration-triggered magnetic phase conversion in the porous Cu(ii)Mn(iii) metal–organic framework

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Article information

DOI
https://doi.org/10.1039/C4DT00222A
Article type
Communication
Submitted
22 Jan 2014
Accepted
26 Feb 2014
First published
27 Feb 2014

Dalton Trans., 2014,43, 6994-6997

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Dehydration-triggered magnetic phase conversion in the porous Cu(II)Mn(III) metal–organic framework

D. W. Ryu, J. H. Shin, K. S. Lim, W. R. Lee, W. J. Phang, S. W. Yoon, B. J. Suh, E. K. Koh and C. S. Hong, Dalton Trans., 2014, 43, 6994 DOI: 10.1039/C4DT00222A

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