Rhenium and technetium bi- and tricarbonyl complexes in a new strategy for biomolecule incorporation using click chemistry†
Abstract
A versatile strategy to prepare fac-[MI(CO)3]+ and cis-[MI(CO)2]+ (M = Re, 99mTc) complexes was developed using Huisgen click chemistry and monodentate phosphine ligands to readily incorporate biomolecules and tailor the chemical properties.