Issue 1, 2014
From the journal:

Energy & Environmental Science

Biomimetic di-manganese catalyst cage-isolated in a MOF: robust catalyst for water oxidation with Ce(iv), a non-O-donating oxidant†

Rebecca E. Hansena  and  Siddhartha Das*a  

* Corresponding authors

a Dept. of Chem. and Biochem., Utah State University, 0300 Old Main Hill, Logan, UT, USA
E-mail: siddhartha.das@usu.edu
Fax: +1 435 797 3390
Tel: +1 435 797 2267

Abstract

A biomimetic di-Mn catalyst catalyzes water oxidation with (NH4)2Ce(NO3)6 for >7 days with initial TOF of 40 h−1. Isolation of one molecule of catalyst in each pore of a Cr-based MOF prevents decomposition of the catalyst and allows sustained water oxidation even at pH 1.00.

Graphical abstract: Biomimetic di-manganese catalyst cage-isolated in a MOF: robust catalyst for water oxidation with Ce(iv), a non-O-donating oxidant

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Article information

DOI
https://doi.org/10.1039/C3EE43040E
Article type
Communication
Submitted
10 Sep 2013
Accepted
30 Oct 2013
First published
04 Nov 2013

Energy Environ. Sci., 2014,7, 317-322

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Biomimetic di-manganese catalyst cage-isolated in a MOF: robust catalyst for water oxidation with Ce(IV), a non-O-donating oxidant

R. E. Hansen and S. Das, Energy Environ. Sci., 2014, 7, 317 DOI: 10.1039/C3EE43040E

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