Issue 98, 2014
From the journal:

RSC Advances

Surfactant-induced chirality on reluctant aggregates of a chiral amphiphilic cationic (l)-proline–Zn(ii)porphyrin conjugate in water†

Edoardo Simoncini,a   Fabrizio Caroleo,a   Francesca Ceccacci,b   Giovanna Mancini,b   Manuela Stefanelli,a   Roberto Paolesse,a   Raffaella Lettieri,a   Mariano Venanzi*a  and  Donato Monti*a  

* Corresponding authors

a Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, Via della Ricerca Scientifica 1, Rome, Italy
E-mail: monti@stc.uniroma2.it
Fax: +39 067259 4328
Tel: +39 067259 4738

b CNR-IMC and Dipartimento di Chimica, Università degli Studi di Roma La Sapienza, P.le A. Moro 5, 00133 Rome, Italy
E-mail: Giovanna.mancini@uniroma1.it

Abstract

Self-assembly of a chiral amphiphilic Zn(II)porphyrin derivative in water gave CD silent species. If the aggregation process occurs in aqueous solutions of chiral surfactants, CD active species are formed with a highly specific molecular recognition effect.

Graphical abstract: Surfactant-induced chirality on reluctant aggregates of a chiral amphiphilic cationic (l)-proline–Zn(ii)porphyrin conjugate in water

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Article information

DOI
https://doi.org/10.1039/C4RA05870D
Article type
Communication
Submitted
17 Jun 2014
Accepted
14 Oct 2014
First published
17 Oct 2014

RSC Adv., 2014,4, 55362-55366

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Surfactant-induced chirality on reluctant aggregates of a chiral amphiphilic cationic (L)-proline–Zn(II)porphyrin conjugate in water

E. Simoncini, F. Caroleo, F. Ceccacci, G. Mancini, M. Stefanelli, R. Paolesse, R. Lettieri, M. Venanzi and D. Monti, RSC Adv., 2014, 4, 55362 DOI: 10.1039/C4RA05870D

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