The self-assembly process from a 1 : 1 to a 1 : 2 complex, facilitated by para-sulfonatocalix[6]arenes (SC6) as host and methyl viologen (MV2+) as guest, was analyzed at the single-molecule level through an α-hemolysin nanopore. Especially, the assembled complex structures were discriminated in real time in the mixture of SC6 and MV2+.
F. Meng, X. Yao, Y. Ying, J. Zhang, H. Tian and Y. Long, Chem. Commun., 2015, 51, 1202 DOI: 10.1039/C4CC07919A
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