Issue 7, 2015
From the journal:

Chemical Communications

Translation of the assembling trajectory by preorganisation: a study of the magnetic properties of 1D polymeric unpaired electrons immobilised on a discrete nanoscopic scaffold†

Vakayil K. Praveen,a   Yohei Yamamoto,*b   Takanori Fukushima,c   Yoshihide Tsunobuchi,d   Koji Nakabayashi,d   Shin-ichi Ohkoshi,d   Kenichi Kato,e   Masaki Takatae  and  Takuzo Aida*af  

* Corresponding authors

a Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
E-mail: aida@macro.t.u-tokyo.ac.jp
Fax: +81-3-5841-7310
Tel: +81-3-5841-7251

b Division of Materials Science and TIMS, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan
E-mail: yamamoto@ims.tsukuba.ac.jp
Fax: +81-29-853-4490
Tel: +81-29-853-5030

c Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

d Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

e RIKEN SPring-8 Center, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan

f RIKEN Center for Emergent Matter Science, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

Abstract

A nitronyl nitroxide (NN)-appended hexabenzocoronene (HBCNN), when allowed to coassemble with bis(hexafluoroacetylacetonato)cobalt(II), forms a coaxial nanotubular architecture featuring NN–Co(II) coordinated copolymer chains immobilised on the outer and inner nanotube surfaces. Upon lowering the temperature, this nanotube has enhanced magnetic susceptibility below 10 K.

Graphical abstract: Translation of the assembling trajectory by preorganisation: a study of the magnetic properties of 1D polymeric unpaired electrons immobilised on a discrete nanoscopic scaffold

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Article information

DOI
https://doi.org/10.1039/C4CC08942A
Article type
Communication
Submitted
09 Nov 2014
Accepted
03 Dec 2014
First published
03 Dec 2014

Chem. Commun., 2015,51, 1206-1209

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Translation of the assembling trajectory by preorganisation: a study of the magnetic properties of 1D polymeric unpaired electrons immobilised on a discrete nanoscopic scaffold

V. K. Praveen, Y. Yamamoto, T. Fukushima, Y. Tsunobuchi, K. Nakabayashi, S. Ohkoshi, K. Kato, M. Takata and T. Aida, Chem. Commun., 2015, 51, 1206 DOI: 10.1039/C4CC08942A

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