The activation of carbon dioxide, organonitriles, and terminal acetylenes by (boryl)iminomethanes derived from isocyanide 1,1-hydroboration is described. Also detailed is the generality of hydroboration of m-terphenylisocyanides with hydroboranes of differing Lewis acidities.
B. R. Barnett, C. E. Moore, A. L. Rheingold and J. S. Figueroa, Chem. Commun., 2015, 51, 541 DOI: 10.1039/C4CC08037H
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