Issue 1, 2015

The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet

Abstract

We report the first near-linear bis(amide) 4f-block compound and show that this novel structure, if implemented with dysprosium(III), would have unprecedented single molecule magnet (SMM) properties with an energy barrier, Ueff, for reorientation of magnetization of 1800 cm−1.

Graphical abstract: The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet

Supplementary files

Article information

Article type
Communication
Submitted
21 Oct 2014
Accepted
05 Nov 2014
First published
05 Nov 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 101-103

The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet

N. F. Chilton, C. A. P. Goodwin, D. P. Mills and R. E. P. Winpenny, Chem. Commun., 2015, 51, 101 DOI: 10.1039/C4CC08312A

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