The mono-alkylation of DPP derivatives leads to cofacial π–π stacking via H-bonding unlike their di-alkylated counterparts, which exhibit a classical herringbone packing pattern. Single crystal organic field-effect transistor (OFET) measurements reveal a significant enhancement of charge carrier mobility for mono-hexyl DPP derivatives.
J. Dhar, D. P. Karothu and S. Patil, Chem. Commun., 2015, 51, 97 DOI: 10.1039/C4CC06063F
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