A convenient, effective, and scalable protocol for stabilizing volatile liquid chemicals is reported. Through the use of halogen-bond driven co-crystal synthesis, several examples of liquid iodoperfluoroalkanes are transformed into crystalline materials with low-vapor pressure, considerable thermal stability, and moisture resistance. The target compounds can subsequently be re-generated through simple solvent-extractions.
C. B. Aakeröy, T. K. Wijethunga, J. Benton and J. Desper, Chem. Commun., 2015, 51, 2425 DOI: 10.1039/C4CC09650A
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