Remote rearrangement of the metal center in a (η6-C6Me6)Ru(II) complex

Koichi Takano; Yousuke Ikeda; Shintaro Kodama; Youichi Ishii

doi:10.1039/C4CC09699A

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Remote rearrangement of the metal center in a (η⁶-C₆Me₆)Ru(ii) complex†

Koichi Takano,^a Yousuke Ikeda,^a Shintaro Kodama^a and Youichi Ishii*^a

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* Corresponding authors

^a Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo, Japan
E-mail: yo-ishii@kc.chuo-u.ac.jp
Fax: +81-3-3817-1895
Tel: +81-3-3817-1901

Abstract

Reaction of [(η⁶-C₆Me₆)RuCl(Ph)(PMe₃)] with internal alkynes in the presence of NaBAr^F₄ gave rise to the 1,4-Ru migration to form the o-vinylaryl complex, providing the first example of 1,4-metal migration of a group 8 metal center; in one case further isomerization to an η³-allyl complex was observed.

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Article information

DOI: https://doi.org/10.1039/C4CC09699A
Article type: Communication
Submitted: 04 Dec 2014
Accepted: 05 Jan 2015
First published: 05 Jan 2015
This article is Open Access

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Chem. Commun., 2015,51, 4981-4984

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Remote rearrangement of the metal center in a (η⁶-C₆Me₆)Ru(II) complex

K. Takano, Y. Ikeda, S. Kodama and Y. Ishii, Chem. Commun., 2015, 51, 4981 DOI: 10.1039/C4CC09699A

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