Issue 18, 2015
From the journal:

Chemical Communications

A facile synthesis of trinaphtho[3.3.3]propellane and its π-extension and the formation of a two-dimensional honeycomb molecular assembly†

Takashi Kubo,*a   Shogo Miyazaki,a   Takuya Kodama,a   Mitsuya Aoba,a   Yasukazu Hiraoa  and  Hiroyuki Kuratab  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan
E-mail: kubo@chem.sci.osaka-u.ac.jp

b Department of Environmental and Biological Chemistry, Faculty of Engineering, Fukui University of Technology, Fukui City, Fukui 910-8507, Japan

Abstract

The multi-gram-scale synthesis of trinaphtho[3.3.3]propellane (TNP) and its π-extension were achieved. X-ray crystallographic analysis revealed that charge transfer complexes of the π-extended TNP with F4-TCNQ form a two-dimensional honeycomb lattice.

Graphical abstract: A facile synthesis of trinaphtho[3.3.3]propellane and its π-extension and the formation of a two-dimensional honeycomb molecular assembly

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Article information

DOI
https://doi.org/10.1039/C4CC09883H
Article type
Communication
Submitted
10 Dec 2014
Accepted
22 Jan 2015
First published
26 Jan 2015

Chem. Commun., 2015,51, 3801-3803

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A facile synthesis of trinaphtho[3.3.3]propellane and its π-extension and the formation of a two-dimensional honeycomb molecular assembly

T. Kubo, S. Miyazaki, T. Kodama, M. Aoba, Y. Hirao and H. Kurata, Chem. Commun., 2015, 51, 3801 DOI: 10.1039/C4CC09883H

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