Issue 18, 2015
From the journal:

Chemical Communications

Diastereoselective synthesis of O symmetric heterometallic cubic cages†

Yang Yang,a   Jian-Hua Jia,b   Xiao-Li Pei,a   Hao Zheng,a   Zi-Ang Nana  and  Quan-Ming Wang*a  

* Corresponding authors

a State Key Lab of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, People's Republic of China
E-mail: qmwang@xmu.edu.cn

b School of Chemistry & Chemical Engineering, Sun Yat-Sen University, Guangzhou, Guangdong, People's Republic of China

Abstract

Enantiopure chiral cubic cages have been diastereoselectively synthesized for the first time. Chiral amines lead to the isolation of O symmetric homochiral cubic cages, while an achiral amine gives a racemic mixture. CD enhancement is observed as a result of configuration rigidity.

Graphical abstract: Diastereoselective synthesis of O symmetric heterometallic cubic cages

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Article information

DOI
https://doi.org/10.1039/C5CC00087D
Article type
Communication
Submitted
06 Jan 2015
Accepted
27 Jan 2015
First published
27 Jan 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 3804-3807

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Diastereoselective synthesis of O symmetric heterometallic cubic cages

Y. Yang, J. Jia, X. Pei, H. Zheng, Z. Nan and Q. Wang, Chem. Commun., 2015, 51, 3804 DOI: 10.1039/C5CC00087D

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