Generally the order of melting point of halogenated compounds is found to be I > Br > Cl whereas, in the series of trihalomesitylenes the order follows as Br > I ≈ Cl. This melting point anomaly has been explained in terms of their thermal expansion behaviours. The order of thermal expansion in this series is found to be Br < I ≈ Cl.
V. G. Saraswatula and B. K. Saha, Chem. Commun., 2015, 51, 9829 DOI: 10.1039/C5CC03033A
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