Issue 7, 2015
From the journal:

Dalton Transactions

Structural and magnetic properties of oxyquinolinate clusters of cobalt(ii) and manganese(ii) and serendipitous intake of carbonate during synthesis†

Prithiviraj Khakhlary,a   Christopher E. Anson,b   Abhishake Mondal,b   Annie K. Powellbc  and  Jubaraj B. Baruah*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781 039, Assam, India
E-mail: juba@iitg.ernet.in

b Institut für Anorganische Chemie, Karlsruher Institut für Technologie, Engesserstr. 15, 76131 Karlsruhe, Germany

c Institute for Nanotechnology, Karlsruhe Institute for Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

During transformation of a tetra-nuclear cobalt oxiquinolinate cluster to a deca-nuclear cobalt oxyquinolinate cluster, serendipitous intake of a carbonate ion was observed. By following a similar synthetic path, a deca-nuclear manganese oxyquinolinate cluster was prepared. These clusters show anti-ferromagnetic behavior.

Graphical abstract: Structural and magnetic properties of oxyquinolinate clusters of cobalt(ii) and manganese(ii) and serendipitous intake of carbonate during synthesis

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Article information

DOI
https://doi.org/10.1039/C4DT02999B
Article type
Communication
Submitted
29 Sep 2014
Accepted
07 Jan 2015
First published
07 Jan 2015

Dalton Trans., 2015,44, 2964-2969

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Structural and magnetic properties of oxyquinolinate clusters of cobalt(II) and manganese(II) and serendipitous intake of carbonate during synthesis

P. Khakhlary, C. E. Anson, A. Mondal, A. K. Powell and J. B. Baruah, Dalton Trans., 2015, 44, 2964 DOI: 10.1039/C4DT02999B

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