Issue 16, 2015
From the journal:

Dalton Transactions

Ascorbic acid decomposition into oxalate ions: a simple synthetic route towards oxalato-bridged heterometallic 3d–4f clusters†‡

Alina S. Dinca,a   Sergiu Shova,b   Adrian E. Ion,a   Catalin Maxim,a   Francesc Lloret,c   Miguel Julvec  and  Marius Andruh*a  

* Corresponding authors

a Inorganic Chemistry Laboratory, Faculty of Chemistry, University of Bucharest, Str. Dumbrava Rosie nr. 23, 020464-Bucharest, Romania
E-mail: marius.andruh@dnt.ro

b “Petru Poni” Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda 41A, RO-700487 Iasi, Romania

c Departament de Química Inorgànica/Instituto de Ciencia Molecular, Facultat de Química de la Universitat de València, C/ Catedrático José Beltrán 2, 46980 Paterna, València, Spain

Abstract

Two types of oxalato-bridged heterometallic 3d–4f dodeca- and hexanuclear compounds have been obtained by connecting six bi- and, respectively, trinuclear moieties through oxalato bridges arising from the slow decomposition of the L-ascorbic acid.

Graphical abstract: Ascorbic acid decomposition into oxalate ions: a simple synthetic route towards oxalato-bridged heterometallic 3d–4f clusters

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Article information

DOI
https://doi.org/10.1039/C5DT00778J
Article type
Communication
Submitted
23 Feb 2015
Accepted
20 Mar 2015
First published
20 Mar 2015

Dalton Trans., 2015,44, 7148-7151

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Ascorbic acid decomposition into oxalate ions: a simple synthetic route towards oxalato-bridged heterometallic 3d–4f clusters

A. S. Dinca, S. Shova, A. E. Ion, C. Maxim, F. Lloret, M. Julve and M. Andruh, Dalton Trans., 2015, 44, 7148 DOI: 10.1039/C5DT00778J

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