Issue 46, 2015
From the journal:

Dalton Transactions

Slight synthetic changes eliciting different topologies: synthesis, structure and magnetic properties of novel dinuclear and nonanuclear dysprosium complexes†

Che-Jung Kuo,a   Rebecca J. Holmbergb  and  Po-Heng Lin*a  

* Corresponding authors

a Department of Chemistry, National Chung Hsing University, 250 Kuo Kuang Rd, Taichung 402, Taiwan
E-mail: po-heng@nchu.edu.tw
Tel: +886-4-22840411, ext. 724

b Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie-Curie, Ottawa, ON, Canada K1N 6N5

Abstract

Using the Schiff-base ligand 1,5-bis(2-hydroxy-3-methoxybenzylidene)carbonohydrazide (H2hmc), dinuclear and nonanuclear compounds, [Dy2(Hhmc)2(NO3)4]·THF·MeCN (1) and [Dy9(μ3-O)4(μ-OH)6(hmc)4(NO3)4(DMF)4](OH)·H2O·THF·DMF (2) are generated through the addition of different bases, respectively. Single-crystal X-ray diffraction analysis revealed a unique Dy9 core structure of complex 2, and the magnetic properties of both compounds are fully studied.

Graphical abstract: Slight synthetic changes eliciting different topologies: synthesis, structure and magnetic properties of novel dinuclear and nonanuclear dysprosium complexes

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Article information

DOI
https://doi.org/10.1039/C5DT02899J
Article type
Communication
Submitted
28 Jul 2015
Accepted
14 Oct 2015
First published
14 Oct 2015

Dalton Trans., 2015,44, 19758-19762

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Slight synthetic changes eliciting different topologies: synthesis, structure and magnetic properties of novel dinuclear and nonanuclear dysprosium complexes

C. Kuo, R. J. Holmberg and P. Lin, Dalton Trans., 2015, 44, 19758 DOI: 10.1039/C5DT02899J

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