The driving force of the unidirectional thermal expansion in KZnB3O6 has been studied experimentally and theoretically. Our results show that the low-energy vibrational modes of alkali metals play a crucial role in this unusual thermal behavior.
Y. Lou, D. Li, Z. Li, H. Zhang, S. Jin and X. Chen, Dalton Trans., 2015, 44, 19763 DOI: 10.1039/C5DT03836G
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